Glossary of Terms
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A2LA - American Association of Laboratory Accreditation - a
non-profit, professional membership society committed to the success of
laboratories through the administration of a broad-spectrum, nationwide
laboratory accreditation system and a full range of training on
laboratory practices taught by experts in their field. Rubberlite’s lab
is accredited.
Accelerated Aging - A test method to represent extended aging
of material in a shorter amount of time. For cellular rubber it is the
process of artificially increasing time to measure physical property
changes. This usually involves exposure to air at an elevated
temperature.
Acrylic Adhesive - A pressure-sensitive adhesive formed by the
polymerization of acrylic ester monomers. These adhesives exhibit high
temperature resistance, excellent U.V. resistance, good plasticizer
resistance and good aging characteristics.
AFMA - American Furniture Manufacturers Association. A
voluntary organization of furniture manufacturers dedicated to fostering
the growth and development of the furniture industry and improving the
effectiveness and efficiency of furniture manufacturers. AFMA was formed
from the merger of the National Association of Furniture Manufacturers
and the Southern Furniture Manufacturers Association.
ANSI - American National Standards Institute. An organization
that verifies that standards developed by other organizations have met
the requirements for due process before approval as an American National
Standard. The use of American National Standards is voluntary.
ASTM - American Society For Testing and Materials. An
organization devoted to the establishment of standard methods and
procedures for testing materials.
Acoustical Flexible Polyurethane Foam - Foam designed to
attenuate, or dampen vibrations or sound waves.
Air Flow - A measure of the ease with which air will pass
through a foam sample. (Test Method ASTM D3574)
Aliphatic - Class of organic chemical compounds containing
carbon, having an open chain molecular structure.
Anti-Oxidants - Materials which when added to a flexible
polyurethane foam formulation improve the resistance of the foam to
oxidative type reactions, such as scorch.
Anti-Static Flexible Polyurethane Foam - Foam that has been
impregnated with electrically conductive materials to prevent static
electricity buildup or promote static dissipation. It is used primarily
in packaging applications, such as electronic components.
Aromatic - Class of organic chemical compounds characterized
by having a benzene, or six membered, ring molecular structure. Toluene
diisocyanate is an aromatic organic compound.
Auxiliary Blowing Agents - Compounds used to produce gases to
expand, or blow, flexible polyurethane foam during production. Most
auxiliary blowing agents are low temperature boiling solvents, such as
chlorofluorocarbons, methylene chloride, methyl chloroform, acetone,
hydrochlorofluorocarbons, and isopentane.
BIFMA - Business and Institutional Furniture Manufacturers
Association. An association of manufacturers of business or
institutional furniture dedicated to the development of voluntary
product safety and performance standards and test methods.
Back Foam - Flexible polyurethane foam used for other than
seat cushioning, usually of a lower density than seating foam.
Ball Rebound - A test procedure used to measure the surface
resiliency of flexible polyurethane foam. The test involves dropping a
steel ball of known mass from a predetermined height onto a foam sample.
The rebound height attained by the steel ball, expressed as a percentage
of the original drop height, is the ball rebound resiliency value. (Test
Method ASTM D3574)
Barrier Material - A barrier placed between a cover fabric and
filling materials to slow heat transfer and flame spread to the filling
material.
Blemish - An imperfection occurring in a cellular rubber
product. It is usually circular in appearance and does not go completely
through the material. Sometimes referred to as a dimple.
Blend Materials - Various polymers used in the manufacture of
cellular rubber materials that are blended together to give a product a
wide range of resistance properties.
Blocks - A cut-off segment of the continuously produced
flexible polyurethane foam being made by the slabstock technique. In
some cases this block would have top, bottom, and side skins intact and
have cut surfaces only on the ends. In other cases, the skins may be
removed by in-line trimmers, leaving a smooth rectangular block.
Blowing - The process by which flexible polyurethane is foamed
during production. The majority of blowing is accomplished in
polyurethanes by adding water to the polyol/toluene diisocyanate
reaction. Water reacts with the toluene diisocyanate to produce carbon
dioxide gas bubbles that expand the polyurethane as it polymerizes.
Auxiliary blowing agents are high volatility liquids that, when added to
the polymerizing liquid, tend to boil and produce large quantities of
gas. The gas produces bubbles as the polymerization takes place,
expanding the liquid resin before it solidifies. Common auxiliary
blowing agents include CFC's and methylene chloride.
Blowing Agent - Various chemicals used in the manufacture of
cellular rubber products that cause the material to expand by giving off
a gas when they are exposed to heat.
Board Foot - Unit of measurement in the flexible polyurethane
foam industry equal to a square foot of material one inch in thickness.
Boardy - Flexible polyurethane foam with a stiff or rigid
feel, generally indicated by high 25% IFD values.
Bolster - A loose pillow, flexible polyurethane foam and/or
fiber filled, that is not attached to the upholstery frame.
Bonded Foam - Flexible polyurethane foam crumbs or shredded
flexible polyurethane foam that has been rebonded to form a salable
product.
Boston Chair Test - Boston Fire Department test method to
measure performance of flexible polyurethane foam padding materials when
exposed to a fairly severe flaming ignition source. This test is a full
scale composite test. Ignition source is four double sheets of newspaper
crumpled inside a paper grocery bag.
Boston Foam - Flexible polyurethane foam filling or padding
material that will meet the requirements of the Boston Fire Department
chair test.
Bottom Out - The lack of support by a flexible polyurethane
foam under full load. This term is very subjective, as a foam may bottom
out with a heavy person, and be very comfortable to a lighter-weight
individual.
Breathability - See Air Flow.
British Standard BS-7176 - British standard specification for
resistance to ignition of upholstered furniture when tested according to
BS-5852. This standard sets the specifications for ignition source
resistance levels for low, medium, and high risk occupancies.
British Test BS-5852 - British Standards Institute test method
for the ignitability of upholstered composites by open flame or
smouldering cigarette sources. BS-5852 is a small scale composite test
of material combinations. Open flame ignition sources range from a match
equivalent butane flame up to a nominal 126 gram wooden crib.
Additionally, a smouldering cigarette is used as an ignition source.
Buffed - Flexible polyurethane foam pieces that have been
shaped or contoured by removal of foam using abrasive or "buffing"
methods.
Bun - See Blocks. Generally, buns are longer than blocks,
approximately equal to or greater than 60 feet in length.
CFC-Free Foam - Flexible polyurethane foams that have been
made without the use of chlorofluorocarbons as auxiliary blowing agents.
California 117 Foam - Flexible polyurethane foam filling
material or padding that will meet the requirements of the California
Bureau of Home Furnishings' Technical Bulletin No. 117.
California Technical Bulletin 116 -California Bureau of Home
Furnishings test method for cigarette ignition resistance of residential
upholstered furniture. This is a small scale composite test.
California Technical Bulletin 117 -California Bureau of Home
Furnishings test method and requirements for open flame and cigarette
resistant materials used in residential upholstered furniture
construction. Cal-117 is a small scale component test. Ignition source
is either an open flame gas burner as specified by Federal Test Method
Standard No. 191, Method 5903.2 or smoldering cigarettes meeting the
cigarette specification of DOC FF4-72.
California Technical Bulletin 133 -California Bureau of Home
Furnishings test method and requirements for open flame resistance of
seating furniture for use in public occupancies in seating areas of ten
or more seats. Cal-133 is a full scale composite test in which physical
design and construction material combinations can affect the test
outcome. Ignition source is five double sheets of newspaper or a
specially designed gas burner as specified in the test method.
Capability (Process) Index, Cp or Cpk - A statistical measure
used to describe the capability of a process to produce a product
(output) within specification tolerance limits. The index is a measure
that indicates high or low process variability. Note: Where k is a
constant number of subgroups of a given size.
Carbon Dioxide Blown Foam -Flexible polyurethane foam in which
all the gas for expanding the foam is carbon dioxide generated by the
chemical reaction between water and the isocyanate material.
Carrier - When referring to double-coated pressure sensitive
adhesive, it is the thin medium to which the adhesive is anchored to on
both sides. One of the most common carriers is Mylar.
Catalyst - A chemical that changes the rate of reaction of a
chemical process, but is not consumed or produced during the reaction.
Cell - The cavity remaining in the structure of flexible
polyurethane foam surrounded by polymer membranes or the polymer
skeleton after blowing is complete.
Cell Count - The number of cells per linear inch or
centimeter, expressed as pores per inch or pores per centimeter.
Cell Size - The average diameter of the cells in the final
flexible polyurethane foam product, often measured in micron units.
Cellular Rubber - Low-density rubber products containing a
cellular structure. The cells may either be open and interconnecting or
closed and not interconnecting; a generic term for materials containing
many cells (either open or closed, or both) dispersed throughout the
mass.
Chemically Blown - A term applying to a cellular material in
which the cells are formed by gases generated from thermal decomposition
or other chemical reaction. In other words and in most cases, a powdered
chemical that is added to a rubber mixture which, when exposed to a
certain temperature, turns into a gas and causes the foam to expand.
Chlorofluorocarbon (CFC) - Chemical compounds that are
chlorine and fluorine substituted alkane hydrocarbons. CFC's are
commonly used as auxiliary blowing agents for foams, refrigerants,
aerosol propellants, and cleaning agents.
Clickability - The ability of a flexible polyurethane foam to
recover from the pinching effects of die-cutting.
Closed Cell Rubber - A rubber product produced by a specific
manufacturing process that utilizes gas forming ingredients in the
rubber compound or by subjecting the compound to a high pressure gas
such as nitrogen. Closed cell rubber is defined as a product whose cells
are totally enclosed by its walls and hence not interconnecting with
other cells. This unique physical property enables closed cell rubber to
function as an excellent seal for moisture, dust, air, gas, smoke,
noise, etc.
Coarse Cell Structure - A term used to describe the appearance
of expanded cellular rubber when the individual cells are larger and/or
spread apart further than normal. Sometimes incorrectly referred to as
Open Cell.
Cold-Cure Foam - See high resiliency foam.
Combustion Modified Foam - Flexible polyurethane foams
manufactured by using additives containing fire suppressants such as
chlorine, bromine, phosphorus, antimony oxide, or some combination
thereof, with or without hydrated alumina or melamine.
Combustion Modified High Resilience Foam (CMHR) - High
resilience flexible polyurethane foams that have been modified for
better flammability behavior by the addition of various flame
retardants.
Compression Force Deflection (CFD) - The determination of the
resistance to compression of a flexible polyurethane foam sample when
the entire surface area of the sample is compressed. Test method is
described in ASTM D3574.
Compression Rate - See Support Factor.
Compression Set - A permanent partial loss of initial height
of a flexible polyurethane foam sample compression due to a bending or
collapse of the cell lattice structure within the foam sample. Large
percentages of compression set will cause a flexible polyurethane foam
cushion to quickly lose its original appearance with use, leaving its
surface depressed or "hollowed out".
Cone Calorimeter - Small, "bench-scale" calorimeter
characterized by its inverted cone shape used to determine heat and
smoke release rates for various materials when exposed to radiant heat.
This is a small scale component test piece of equipment.
Constant Deflection Compression Set -Test used to determine
the amount of foam recovery from a static or fixed compression. Test
method is described in ASTM D3574.
Conventional Flexible Polyurethane Foam -Polyether type
polyurethane foams made by the basic manufacturing process with no
additives.
Conventional California or FR Foam - Conventional flexible
polyurethane foams to which fire retardants have been added.
Converter - One that is employed in changing a raw material
into another form of product.
Convoluted - A fabrication process in which flexible
polyurethane foam is cut while compressed non-uniformly to produce a
surface with a multicontoured texture. This texture gives the foam a
different surface feel, or apparent softness.
Cross-linking - The bonding of molecules into a structure.
This gives the polymer increased strength resulting in superior
properties. Crosslinking can achieved by either physical (irradiation by
an electron beam) or by chemical means.
Cure - For cellular rubber, the time period and temperature in
which various chemical reactions (e.g. cross-linking) occurs. This phase
of a process is critical as too much time will produce an over-cured
product and too little time will produce an under-cured product.
DOT MVSS-302 - Department of Transportation Motor Vehicles
Safety Standard in which the test sample is ignited in a horizontal
position by a calibrated gas flame for 15 seconds. Burn length, time and
speed are determined and sample is classified by the outcome. This is a
small scale component test developed for automotive interior materials.
Deflect - To compress, usually by a specified amount or
percentage.
Delamination - The undesirable separation or buckling of the
release liner from an adhesive layer usually in the parallel direction
of the web. Most often found during high humid conditions causing the
paper to grow.
Densified - A material that has been made more dense by
permanently compressing a unit mass into a smaller volume.
Densified foam - Sometimes called felted foam, it is foam that
has been permanently compressed through a precisely controlled thermal
setting process.
Density - The mass of a substance divided by its volume. In
the United States, density is accepted as the weight of a substance
divided by its volume. Foam density is often expressed as pounds per
cubic foot or kilograms per cubic meter. (Test Method ASTM D3574)
Dish - Description of what occurs when a weight is placed on
the center of a cushion and the corners of the cushion rise up in
response.
Double-Coated - A pressure-sensitive adhesive consisting of a
carrier with similar or dissimilar adhesives applied to both surfaces.
Double Tee - See Tee.
Durometer - An instrument used to measure hardness of elastic
materials. Durometer is also used to reference a scale of hardness; ie,
a low durometer implies a soft material.
Dynamic Flex Fatigue - See Fatigue.
ECH - Epichlorohydrin. A polymer used in the manufacture of
cellular rubber. Its primary characteristics are resistance to swell
when exposed to fuel and high temperature resistance up to 325ºF.
Elastomer - Polymers which resist and recover from deformation
produced by force, similar in behavior to natural rubber.
Elephant Skin - Surface creasing effect due to lateral
resistance of a stiff, thick flexible polyurethane foam when compressed
parallel to its face.
Elongation - The percent that a specially shaped sample will
stretch from its original length before breaking. (Test Method ASTM
D3574)
Environmentally Safe - Flexible polyurethane foam processed
with no auxiliary blowing agents.
EPDM - Ethylene Propylene Diene. A polymer used in the
manufacture of cellular rubber. It has excellent resistance to sunlight,
ozone and heat, and good resistance to alkalis and acids.
EVA - Ethylene Vinyl Acetate. It is generally used as a
co-polymer in polyolefin foams resulting in greater resilience and
higher tensile and tear performance.
Exotherm - The heat released as a by product of some chemical
reactions. Flexible polyurethane foam producing reactions are
exothermic.
Expanded Rubber - A term reserved for closed-cell compounds
that are made by incorporating gas-forming ingredients in the rubber
compound or by subjecting the compound to high-pressure gas, such as
nitrogen. These materials are manufactured in sheet, roll, strip,
molded, and special shapes by molding or extrusion.
Extrusion - Material that is formed by being forced through a
shaping orifice as a continuous body.
FIRA - Furniture Industry Research Association - A voluntary
British organization of interested parties involved in flammability
research, creating methods of testing and establishing specifications
for flammability performance of upholstered furniture.
Fabricator - One that constructs a finished product by
combining, assembling or processing a raw material.
Fatigue - A tendency to soften under cyclic stresses. Fatigue
of foam samples can be measured by cyclicly compressing and relaxing a
flexible polyurethane foam sample and measuring its change in IFD.
Feel - See Hand. Felted - Flexible polyurethane foam that has
been densified by heat and compression for use as a vibration dampening
or shock absorbing material.
Felted - Flexible polyurethane foam that has been densified by
heat and compression for use as a vibration dampening or shock absorbing
material.
Filled Flexible Polyurethane Foam - Flexible polyurethane
foams that have inorganic materials, such as marble dust, barium
sulfate, graded sand or clay added to the foam during polymerization to
increase foam density. These inorganic fillers are not chemically bonded
into the foam polymer. They are instead mechanically trapped within the
molecular structure of the polymer. Substantial amounts of filler may
increase the foam's support factor, but may be detrimental to
resiliency, strength, or durability.
Filler - The inorganic materials added to foam to increase
foam density.
Finger Nail - A quick, general test for boardiness or stiff
surface feel flexible polyurethane foam. A finger nail pressed into a
foam sample that leaves a definite impression that does not quickly
recover indicates a boardy foam.
Fire Retardants - A material that, when added to flexible
polyurethane foam, will cause the foam to be more difficult to ignite or
burn less rapidly or lose less weight during a fire than without that
material.
Flammability - The characteristics of a material that pertain
to its relative ease and relative ability to sustain combustion.
Flat Top - A block or bun of flexible polyurethane foam that
is essentially flat on the top surface when poured, as opposed to having
an arched top when allowed to free rise.
Flex Fatigue - See Fatigue.
Flexible PUF - Flexible polyurethane foam.
Fluid Immersion Test - The submersion of a piece of cellular
rubber in Fuel B (similar to Jet Fuel). The foam is weighed before and
after and the test measures the amount of fuel absorbed by the material.
The lower the % of mass gain, the better the resistance to petroleum
based fuels.
Foam - A product, either flexible or rigid, that has been
produced by the internal generation of a gas in a fluid medium that is
polymerizing while expanding in volume. The final result is either an
open or closed-cell product.
Graft or Polymer Polyol - Polymers with active hydroxyl groups
that have other organic groups or polymers "grafted" to the polyol
molecule. These grafted organic compounds serve to reinforce the
strength or modify other properties of the flexible polyurethane
product.
Guide Factor - GF = 25% IFD divided by density determined
after one minute rest.
Guts - Flexible polyurethane foam that has adequate support
under load and does not "bottom out" is said to have "guts".
HCFC's - Non-fully halogenated chlorofluorocarbons that are
used as substitutes for CFC's in foam blowing. Theoretically, HCFC's
have a lower ozone-depletion potential to the environment than do "hard"
fully halogenated CFC's.
Hand - Hand is the feel of the surface of flexible
polyurethane foam when rubbed lightly. Stiff or hard feel is poor hand.
Good hand is described as a springy, velvet feel.
Hardness - The resistance to indentation, as measured under
specific conditions.
Hardness Index - Synonym for the 50% IFD value. Some furniture
designs are for a maximum 50% indentation while some are for only a 20%
indentation, ie., chairs versus bar stools.
High Resilience (HR) Foam - Flexible polyurethane foam that
has a very rapid recovery from extreme compression and a fairly linear
increase in resistance to compression per unit of penetration. (See ASTM
D-3770).
Hook - A wedge shaped foam extension on cushion units used to
make cushions conform to the shape of a back.
Humid Aging - An accelerated aging test under conditions of
high humidity and temperature. ASTM D3574 describes the test method.
Hydrolytic Degradation - The degradation of flexible
polyurethane foam by hydrolysis or disassociation by water under
conditions of constant exposure. The humid aging test method was
developed to attempt to measure the effects of hydrolytic degradation.
Hydrophilic - An affinity for water.
Hydrophobic - A repellency for water.
Hysteresis - The ability of a flexible polyurethane foam to
return to its original support characteristics after it is compressed.
Hysteresis = (25%)
IFD initial - 25% IFD after compressing 65% of initial
height)/25% IFD initial * 100.
IAFF - International Association of Fire Fighters.
Indentation Force Deflection (IFD) - A measure of the load
bearing capacity of flexible polyurethane foam. IFD is generally
measured as the force (in pounds) required to compress a 50 square inch
circular indentor foot into a four inch thick sample no smaller than 24
inches square, to a stated percentage of the sample's initial height.
Common IFD values are generated at 25 and 65 percent of initial height.
Reference Test Method ASTM D3574.
Indentation Load Deflection (ILD) - See Indentation Force
Deflection.
Indentation Modulus - IM = (40%IFD-20%IFD)/20%IFD. The force
required to produce an additional 1% indentation between the limits of
20% IFD and 40% IFD determined without the one minute rest. The slope of
this line represents the resistance of the cell struts to post buckling.
The slope of the linear portion of the stress-strain curve is defined as
the indentation modulus.
Indentation Residual Deflection Force (IRDF) -A test method
used with seating foam to determine how thick the padding is under the
average person. The amount of deflection is determined by measuring the
thickness of the pad under fixed force of 4.5 Newtons, 110 N, and 220 N
on a 323 square centimeter circular indentor foot.
Initial Hardness Factor - IHF = 25%IFD/5%IFD determined
without the one minute rest. This ratio defines the surface feel of a
flexible foam. Soft surface foam will have a high IHF value, while stiff
or boardy surface foams will have a low IHF value.
Initial Softness Ratio - See Initial Hardness Factor.
Interior Density - The density of a foam sample at its center.
Generally, a foam will form a density gradient, with the highest density
being at the outer, or skin surface, and the lowest density being at the
core of the foam sample.
JIPFSC - Joint Industry Polyurethane Foam Standards Committee.
A voluntary standards organization formed under the auspices of the
American Furniture Manufacturers Association, dedicated to the
development of flexible polyurethane foam standards, guidelines, test
methods, classifications, and definitions for the furniture industry.
K Factor - A measure of the thermal conductivity of heat
insulation expressed as BTUs/sq. ft. Lower values indicate better
insulating materials.
Lamination - A fabrication process bonding two foam types, or
a foam and another substrate, using an adhesive.
Latex Foam - A latex rubber foam product not related to
flexible polyurethane foams.
Leveling - The process of taking raw material rubber products
and skiving thin cuts of material from it until the rubber is uniform in
thickness.
Life Safety Code - A collection of specifications and test
methods relating to fire safety in buildings and structures compiled by
the National Fire Protection Association.
Loop Splitter - A mechanical splitter which allows continuous
slitting of long buns of foam.
MDI - An abbreviation for 4,4-diphenylmethane diisocyanate, it
is often mixed with toluene diisocyanate in the production of molded
flexible polyurethane foam cushions.
Maxfoam - A foam manufacturing process utilizing a trough and
fall plate system for efficient foam manufacturing. See Varimax
Melamine.
Melamine Foam - Flexible polyurethane foam incorporating
melamine powder as a filler primarily as a fire retardant.
Methylene Chloride - A non-flammable, low-boiling chlorinated
hydrocarbon solvent used as an auxiliary blowing agent in flexible
polyurethane foam production.
Modulus - See Support Factor.
Modulus Irregularity Factor - MIF = 2 * 20%IFD - 40%IFD. The
MIF is the extrapolated intercept of the stress axis, or y axis, of the
linear portion of the stress-strain curve. If the MIF is zero, the
indention modulus is essentially constant, and the stress-strain curve
is linear and passes through the origin. If the indentation modulus
varies at low levels of strain before reaching a constant value at above
approximately 10 per strain, the MIF will either be a positive or
negative value. The degree of deviation of the MIF from zero describes
the shape of the lower end of the stress-strain curve, and thus the
performance of cushioning for some seating applications.
Modulus of Compression (MOC) - See Support Factor.
Molded Foam - A cellular foam product having the shape of the
mold cavity in which it was produced.
MVSS-302 - Motor Vehicle Safety Standard. This specification
(302) describes test procedures used to determine the burn rate of
parts, portions of parts, and composites used as interior trim parts in
passenger cars, multipurpose passenger vehicles, trucks and buses.
NFPA - National Fire Protection Association.
NFPA 260 - National Fire Protection Association test method
for determining resistance to cigarette ignition for materials used in
upholstered furniture. This test is a small scale composite test.
Ignition source is a smoldering cigarette.
NIST - National Institute for Standards and Technology,
formerly the National Bureau of Standards.
Natural Rubber - Derived from botanical sources, primarily
from the Heavea brasiliensis tree.
Neoprene (CR) (NEO) - Polychloroprene. A synthetic rubber
discovered by the Du Pont Company in 1931. It is a polymer composed of
carbon, hydrogen and chlorine. Its features include resistance to
petroleum based fluids and flame resistance.
Nitrile Rubber (NBR) - Emulsion copolymers of Butadiene and
Acrylonitrile in varying proportions. This chemical is used in the
manufacture of expanded rubber primarily for its resistance to swelling
in oils and solvents.
OSU Calorimeter - Calorimeter developed at Ohio State
University for determination of heat and visible smoke release rates for
various materials when exposed to different levels of radiant heat. The
test method for using the OSU calorimeter is published under ASTM E-906,
and is a small scale component test.
Oozing - Concerning PSA’s, refers to the condition where the
sides of a roll become sticky or tacky due to the flowing out of
adhesive between the layer of tape.
Open Cell Material - A rubber product produced by a specific
manufacturing process that utilizes a chemical blowing agent that
expands the mass during the vulcanization process. Open cell rubber is
defined as materials whose cells are not totally enclosed by its walls
and open to the surface, either directly or by interconnecting with
other cells. The primary characteristics are that water, air or gas can
pass through, much like the way water is absorbed by a dish sponge. This
type of material is also excellent for padding and cushioning
applications where low compression set is required.
Organotin Catalysts - A family of organic tin compounds used
as catalysts in flexible polyurethane foam production that have a
specific influence on the rate of the gelation reaction. Members include
stannous octoate, dibutyltin dilaurate, dibutyltin diacetate, and
dibutyltin diethyl hexoate.
Over-cure - For cellular rubber, the time period or
temperature in which various chemical reactions which occur (e.g.
cross-linking) last too long. The result is blisters, too tight of a
cell structure, voids along the edges, etc. This problem is most
apparent on the edges of a material.
Ozone Resistance - The ability of a material to resist
sunlight and/or outdoor exposure.
PFA - Polyurethane Foam Association. A trade association of
the manufacturers of flexible polyurethane foam and their suppliers of
goods and services.
Permeability - The rate at which a liquid or gas can penetrate
into or through a flexible polyurethane foam. Usually associated with
airflow, a measure of the openness of the foam.
Pieced - Flexible polyurethane foam that has been glued
together from two or more smaller pieces. Commonly seen in cushioning to
create special shapes or use up small pieces produced during
fabrication.
Plasticizer - Chemical additives in a flexible polyurethane
foam formulation that generally serve to increase the flexibility of the
foam structure.
Plasticizer Migration - Loss of plasticizer from an
elastomeric compound. It often migrates to the surface of the material
where it is absorbed by another product or evaporates. This process
causes the material to lose its flexibility and can contaminate other
products.
Polyester - A family of organic polymers characterized by the
presence of ester groups O " R-C-O-R within the molecule. Polyesters can
be prepared to have reactive hydroxyl groups and thus can be used as a
polyol in the preparation of urethane foam. Esters are more susceptible
to hydrolysis than are ethers.
Polyether - A family of organic polymers characterized by the
presence of ether groups R-O-R within the molecule. Polyethers can be
prepared to have reactive hydroxyl groups and thus can be used as a
polyol in the preparation of polyurethane foam. Ethers are less
susceptible to hydrolysis than esters.
Polyethylene - A thermoplastic composed of polymers of
ethylene.
Polymer - In dealing with sponge rubber, this is a large
molecular chain made up of two or more monomers. These monomers are
polymerized or chemically reacted to form a material that is
significantly different than either of the two base monomers from which
it was made.
Polymeric Foam - See High Resilience Foam.
Polyol - A chemical compound having more than one reactive
hydroxyl group within the molecule. Polyol usually refers to a glycerine
based product with three reactive hydroxyl groups.
Polypropylene - Any of various thermoplastic resins that are
polymers of propylene. Propylene is a flammable gas derived from
petroleum hydrocarbon cracking and used in organic synthesis.
Polypropylene Glycol - A propylene based diol having two
reactive hydroxyl groups per propylene unit.
Polyurethane - Any of various thermoplastic or thermosetting
resins, widely varying in flexibility, used in tough chemical-resistant
coatings and in adhesives, foams, and electrical insulation.
Polyurethane Fillers - See Fillers.
Pores Per Inch (ppi) - Unit for expressing cell count of a
foam.
Porosity - The presence of numerous small cavities within a
material. See Air Flow.
Pounding Fatigue - Accelerated fatigue aging of flexible
polyurethane foam by cyclicly compressing samples to a specified
percentage of their original height and releasing for a specified number
of repetitions.
Preflex - The practice of compressing a flexible polyurethane
foam sample once or twice to a predetermined thickness before
determining IFD.
Pressure Sensitive Adhesive (PSA) - A term used to designate a
distinct category of adhesive tapes which in dry (solvent free) form are
aggressive and permanently tacky at room temperature and adhere to a
variety of surfaces without the need of more than finger or hand
pressure. They require no activation by water, solvent or heat and have
sufficient cohesive strength so they can be handled with the fingers.
PUF - Polyurethane Foam.
PVC - Polyvinyl chloride. A polymer used in the manufacture of
expanded rubber. This compound is inherently fire retardant because of
its high chlorine content.
Rate of Heat Release (RHR) - The quantity of energy released
in a given amount of time from a burning sample, used in flammability
studies. Units include BTU/hour, calories per second, joules per second,
or watts. Values are determined by calorimetry, including cone
calorimetry or the Ohio State University furniture calorimeter.
RE - Terminology derived from the ASTM-D-1056-65
specification. The R stands for cellular rubbers made from natural
rubber, synthetic rubber or rubber-like materials, alone or in
combinations where specific resistance to the action of petroleum based
oils is not required. The E is a designation for closed-cell material.
Rebonding - The process of adhering flexible polyurethane foam
crumbs or shredded foam back together again to make a salable product.
Rebonded foam is often used for carpet padding.
Recovery - The return to original dimension and properties of
a flexible polyurethane foam sample after a deforming force is removed.
Reinforced Foam - See Filled Flexible Polyurethane Foam.
Resiliency - The ability of a surface to spring back to its
original shape after being deformed and released. The resiliency of
flexible polyurethane foam is measured using the ball rebound test.
Reticulated Foam - Flexible polyurethane foams characterized
by a three-dimensional skeletal structure with few or no membranes
between strands. Reticulated foams are generally used as filters,
acoustical panels, and for controlled liquid delivery.
RO - Terminology derived from the ASTM-D-1056-65
specification. The R stands for cellular rubbers made from natural
rubber, synthetic rubber or rubber-like materials, alone or in
combinations where specific resistance to the action of petroleum based
oils is not required. The O is a designation for open-cell material.
Roller Shear - Procedure that fatigues a flexible polyurethane
foam specimen dynamically at a constant force, deflecting the material
both horizontally and vertically. See ASTM D- 3574
Roll Goods - Flexible polyurethane foam that has been peeled
or slit from a foam "log" and rolled onto a core for handling purposes.
Rolled foam sheets are commonly used for large area padding, such as
carpet padding.
Rubber - A material that is capable of recovering from large
deformations quickly and forcibly, and can be, or already is, modified
to a state in which it is essentially insoluable (but can swell) in
boiling solvent.
Rubber Based Adhesives - An adhesive made from one or more
synthetic or natural elastomers and tackifiers to produce a
pressure-sensitive adhesive. These adhesives are characterized by having
higher quick tack and adhesion than acrylics, however, they lack aging
and weather resistance.
SBE - Terminology derived from the ASTM-D-1056-65
specification. The SB Designation stands for cellular rubbers made from
synthetic rubber or rubber-like materials having oil resistance with low
swell. The E is a designation for closed-cell material.
SBR - Styrene-butadiene rubber. A polymer used in the
manufacture of expanded rubber. It is very economical and possesses no
unique chemical resistance properties.
SCE - Terminology derived from the ASTM-D-1056-65
specification. The SC Designation stands for cellular rubbers made from
synthetic rubber or rubber-like materials having oil resistance with
medium swell. The E is a designation for closed-cell material.
SPI - Society of the Plastics Industry. A national
organization of companies and individuals in the plastics industry that
is oriented toward developing industry standards and test methods.
Scorch - Discoloration in center of foam buns due to oxidation
of the polymer during manufacture.
Seam - The splice line formed by two or more separate pieces
of flexible polyurethane foam that have been bonded together.
Seat Foam - Flexible polyurethane foam used for seat cushions.
Section Density - Density of a flexible polyurethane foam
taken from the cross section of a bun with top and bottom skins intact.
Self-Extinguishing - A somewhat loosely used term describing
the ability of a material to cease burning once the source of flame has
been removed.
Shelf Life - The period of time that a product can be stored
under specific conditions and still remain suitable for use.
Shiners - Light reflected from intact cell walls, noticable on
the cut surfaces of flexible polyurethane foam. A large number of
shiners, or shiny spots, indicates a foam with many closed cells.
Shredded Foam - Flexible polyurethane foam that has been
mechanically torn into small pieces or crumbs, for the purpose of
creating a loose filling material.
Shrinkage - An inadvertent dimensional decrease of cellular
structure without an actual breakdown or collapse of the cell. This
characteristic is relatively common in all cellular rubber and plastic
products. The primary cause is the equalization of pressure from the
manufacturing process to normal atmospheric pressures.
Silicone - A rubber made from silicone elastomers and noted
for its retention of flexibility, resilience, tensile strength and wide
temperature range.
Silicone Foam - Organosilicon polymers that are expanded or
blown during the polymerization of silicone rubber.
Silicone Surfactant - Complex organosilicon compounds that
exhibit surface active properties when used in polyurethane foam
formulations. These compounds add stability to the liquid foaming
mixture so that collapse of bubbles is retarded and flowability is
increased.
Skin - The higher density outer surface of the flexible
polyurethane foam slab, resulting from surface cooling during
polymerization.
Skive - To shave or cut off the surface of a rubber material
in a horizontal manner. Sometimes referred to as splitting which means
to divide sharply or cleanly into layers.
Slitting - The action of cutting material to width.
Slab Stock - Flexible polyurethane foam made by the continuous
pouring of mixed liquids onto a conveyor, creating a continuous loaf of
foam.
Splits - Horizontal tears or rips in the side of the flexible
polyurethane foam block, either intermittent or continuous along the
side of the slab, commonly caused by excessive speed of the blowing
reaction or too steep an angle of rise.
Sponge Rubber - A cellular rubber consisting predominantly of
open cells made from a solid rubber compound. These products are
manufactured in sheet, roll, strip, and molded or special shapes.
Sometimes referred to as foam rubber.
Static Fatigue - The loss in load bearing properties of a
flexible polyurethane foam sample under constant compression of 75% for
17 hours at room temperature. See Test Method ASTM D-3574
Static Force Loss - See Static Fatigue.
Stripping - A product and/or process of producing a long,
narrow piece of material that is uniform in width. Sometimes referred to
as slitting.
Substrate - The surface to which a pressure-sensitive tape,
fabric, foam, etc. is applied.
Support Factor - Support Factor = 65%IFD/25%IFD determined
after one minute of rest or recovery. When based on 25% IFD values, the
support factor indicates the 65% IFD values that will be attained by the
foam. Seating foams with low support factor are more likely to bottom
out under load.
TDI - An abbreviation for toluene diisocyanate, TDI is one of
the two primary reactants involved in the production of flexible
polyurethane foams.
Tear Strength - The ability of a piece of flexible
polyurethane foam to resist propagation of a cut made in the sample.
Reference ASTM D-3574
Tee - Horizontal extension on the front edge of cushion that
extends in front of arms or stumps of chair or sofa frames.
Temperature Range - The minimum and maximum temperature that a
material can be exposed to before the physical properties and/or
appearance begins to move out of their specification range.
Tensile Strength - The pounds per square inch of force
required to stretch a material to the breaking point. Reference ASTM
D-3574
Thermal formable - To change the shape and/or structure of a
material using heat and a suitable mild structure.
Tight Foam - Flexible polyurethane foam with many closed
cells, resulting in low air flow measurements.
Tolerance - The permissible deviation from a specified value
of a dimension.
Transfer Tape - An unsupported pressure-sensitive adhesive on
a release liner that has been release coated on both sides.
UFAC - Upholstered Furniture Action Council. A voluntary
furniture industry association organized to conduct research into more
cigarette resistant upholstered furniture.
UL - Underwriters Laboratories. An independent, non-profit
organization testing for public safety. UL is chartered to establish,
maintain, and operate laboratories for the examination and testing of
devices, systems, and materials to determine their relation to hazards
to life and property.
UL-94 HBF - Underwriters Laboratories test method in which the
test sample is ignited for one minute with a calibrated gas flame.
Sample is classified by burn time, length, and glowing combustion time
after the flame is removed. This is a small scale component test.
UL-94 HFI - Test method similar to UL-94 HBF, with the
additional requirement that no flaming drippings are allowed which would
ignite cotton placed below the test specimen.
UL-1056 - Underwriters Laboratories test method for the
ability of upholstered furniture to resist rapid heat release when
subjected to a flaming ignition source. UL-1056 is a full scale
composite test in which physical design and material combinations may
affect the test outcome. Ignition source is a nominal 340 gram wood
crib.
Under cure - For cellular rubber, when the time period in
which various chemical reactions occurring (e.g. cross-linking) does not
last long enough. The result is a loose cell structure, a mushy
appearance, etc. This problem is most apparent in the center of a
material and this area will often collapse after skiving.
Urea - Urea is a by product of the water-toluene diisocyanate
reaction during flexible polyurethane foam production. The urea forms
short length polymer cross links between the long polyurethane chains,
which adds firmness to the foam.
Urethane - A colorless, crystalline substance used primarily
in medicines, pesticides, and fungicides. Urethane is not used in the
production of urethane polymers or foams. The urethanes of the plastics
industry are so named because the repeating units of their structures
resemble the chemical urethane.
Varimax - A foam manufacturing process utilizing Maxfoam
technology with the addition of moveable sidewalls for greater
processing flexibility.
Vertifoam - A foam manufacturing process utilizing Maxfoam
principles where the direction of foaming is vertical.
Vinyl - A chemical derived from ethylene and used as a basic
material for plastics that are typically tough, flexible, shiny and
often used for coverings and clothing.
Voids - The presence of numerous small cavities within a
material.
Vulcanization - An irreversible process during which a rubber
compound, through a change in its chemical structure, e.g.
cross-linking, becomes less plastic and more resistant to swelling by
organic liquids. The result is that elastic properties are improved or
extended over a wide range of temperatures. Vulcanization can be carried
out under numerous conditions but it usually involves heat.
Water Absorption Test - The process of submerging a piece of
cellular rubber in distilled water and exposing it to increased
atmospheric pressure. The foam is weighed beforehand and afterwards. The
test measures the amount of water absorbed by the material. The lower
the %, the less water the material absorbs.
Water Blown Foam - Flexible polyurethane foam in which the gas
for expansion is carbon dioxide generated by the reaction between water
and an isocyanate material. All flexible polyurethane foam is
waterblown, although auxiliary blowing agents are often used to obtain
special physical properties.
Wedge - See Hook
Z Suffix - A suffix within ASTM-D-1056 used for special
requirements. The test methods and values are to be arranged between the
manufacturer and the purchaser.
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